916152-74-4Relevant academic research and scientific papers
Further studies on enantioselective synthesis of (+)-anatoxin-a using enyne metathesis: unexpected inversion of chirality via a skeletal rearrangement of 9-azabicyclo[4.2.1]nonene derivative
Tomita, Tomohiro,Kita, Yoichi,Kitamura, Tsuyoshi,Sato, Yoshihiro,Mori, Miwako
, p. 10518 - 10527 (2007/10/03)
The formal total synthesis of (+)-anatoxin-a was accomplished using enyne metathesis as a key step. It is very interesting that (+)-anatoxin-a was synthesized from (S)-pyroglutamic acid via an unusual inversion of chirality, which is rationalized in terms
