91632-86-9Relevant academic research and scientific papers
THE CONFORMATION OF N-NITROSO-N-METHYLANILINE FROM MICROWAVE SPECTROSCOPY
Caminati, W.,Giumanini, A. G.
, p. 255 - 262 (1987)
The low resolution microwave spectrum of N-nitroso-N-methylaniline shows only one series of μa R-branch bands.The value of B + C = 1584.6 MHz is consistent with this being the rotamer in which the benzene ring is exo to the nitroso group.The high resolution microwave spectra of the normal, CD3 and two meta-D species show conclusively that this rotamer has a non-planar heavy atom skeleton.The rotational constants, the quantity Δc (= Ia + Ib - Ic) and the substitution coordinates are well reproduced by a molecular model based on the structures of aniline and N,N-dimethylnitrosamine in which the plane of the benzene ring is twisted by 30 deg relative to the heavy atom plane of the rest of the molecule.
Method for preparing deuterated amine compound by using microwave reaction device
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Paragraph 0071; 0074, (2019/05/28)
The invention provides a method for preparing a deuterated amine compound. The method comprises the step of converting a non-deuterated amine compound containing at least one structure of formula C-N-X into the deuterated amine compound by using a microwa
