916335-79-0Relevant academic research and scientific papers
Probing the limits of rate acceleration mediated by hydrogen bonds
Cowie, Rosalyne M.,Turega, Simon M.,Philp, Douglas
, p. 5179 - 5182 (2007/10/03)
A simple receptor and substrate are used to probe the relationship between transition-state charge and the level of rate acceleration that can be created by stabilizing the transition state through hydrogen bonding. Pericyclic reactions are accelerated le
