916463-25-7Relevant articles and documents
Exceptional rate enhancements and improved diastereoselectivities through chelating diamide coordination in intramolecular alkene hydroaminations catalyzed by yttrium and neodymium amido complexes
Kim, Young Kwan,Livinghouse, Tom
, p. 3645 - 3647 (2002)
Modification of the metal center in the complexes [Ln{N(TMS)2}3] (Ln = Y, Nd; TMS = trimethylsilyl) is readily achieved by amine elimination in the presence of sterically hindered chelating diamines to provide complexes with substantially augmented catalytic activities and improved stereoselectivities in intramolecular alkene hydroamination (see scheme).