916463-25-7Relevant academic research and scientific papers
Exceptional rate enhancements and improved diastereoselectivities through chelating diamide coordination in intramolecular alkene hydroaminations catalyzed by yttrium and neodymium amido complexes
Kim, Young Kwan,Livinghouse, Tom
, p. 3645 - 3647 (2002)
Modification of the metal center in the complexes [Ln{N(TMS)2}3] (Ln = Y, Nd; TMS = trimethylsilyl) is readily achieved by amine elimination in the presence of sterically hindered chelating diamines to provide complexes with substantially augmented catalytic activities and improved stereoselectivities in intramolecular alkene hydroamination (see scheme).
