916518-57-5Relevant articles and documents
Transition-Metal-Free ipso-Trifluoromethylthiolation of Lithium Aryl Boronates
Shen, Feng,Zheng, Hanliang,Xue, Xiao-Song,Lu, Long,Shen, Qilong
supporting information, p. 6347 - 6351 (2019/08/20)
A transition-metal-free direct trifluoromethylthiolation of the ipso-carbon of lithium aryl boronates with trifluoromethanesulfenate under mild conditions was described. In addition, late-stage site-selective C-H borylation/trifluoromethylation and C-Cl b
Ni-Catalyzed Borylation of Aryl Fluorides via C-F Cleavage
Liu, Xiang-Wei,Echavarren, Javier,Zarate, Cayetana,Martin, Ruben
supporting information, p. 12470 - 12473 (2015/10/19)
A Ni-catalyzed borylation via C-F activation is described. This protocol is distinguished by a wide scope, including unactivated fluoroarenes, without compromising its efficiency and scalability, thus representing a significant step-forward toward the implementation of C-F activation protocols.
Borylation of aryl and alkenyl carbamates through Ni-catalyzed C-O activation
Huang, Kun,Yu, Da-Gang,Zheng, Shu-Fang,Wu, Zhen-Hua,Shi, Zhang-Jie
experimental part, p. 786 - 791 (2011/03/20)
Direct borylation of aryl/alkenyl carbamates was developed through Ni catalysis. A broad substrate scope, including aryl, alkenyl, and heterocyclic derivatives, was studied. This study offers a convenient method to approach aryl/alkenyl boronic esters from phenol and ketone derivatives (see scheme). Copyright