916603-00-4

Basic information

• Product Name: chloro(1,5-cyclooctadiene)(4-phenylimine-4'-pyridine)rhodium
• CAS NO: 916603-00-4
• Molecular Weight: 428.767
• Mol File: 916603-00-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: chloro(1,5-cyclooctadiene)(4-phenylimine-4'-pyridine)rhodium(CAS DataBase Reference)
• NIST Chemistry Reference: chloro(1,5-cyclooctadiene)(4-phenylimine-4'-pyridine)rhodium(916603-00-4)
• EPA Substance Registry System: chloro(1,5-cyclooctadiene)(4-phenylimine-4'-pyridine)rhodium(916603-00-4)

Safety Data

• Hazardous Substances Data: 916603-00-4(Hazardous Substances Data)

Upstream product

• 27768-46-3 N-(pyridin-4-ylmethylene)aniline 

Relevant articles and documents

Ferrocenyl-nitrogen donor ligands. Synthesis and characterization of rhodium(I) complexes of ferrocenylpyridine and related ligands

The preparation of a series of complexes of the types [RhCl(CO)2(L)], [RhCl(cod)(L)] and [Rh(cod)(L)2]ClO4, where L is a ligand incorporating a ferrocenyl group and a pyridine ring is described. Complexes were characterized using NMR, IR and electronic spectroscopy. The electrochemical behaviour of the complexes was examined using cyclic voltammetry. The X-ray structures of three of the complexes, [RhCl(CO)2{NC5H4C{double bond, long}NC6H4(η5-C5H4 )Fe(η5-C5H5)}], [RhCl(cod)(3-Fcpy)] and [RhCl(cod){3-Fc(C6H4)py}], were determined.