916657-16-4

Basic information

• Product Name: [Cu(2,9-dimethyl-1,10-phenanthroline)2][tris(4-hydroxyphenyl)ethane^(1-))]
• CAS NO: 916657-16-4
• Molecular Weight: 785.425
• Mol File: 916657-16-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Cu(2,9-dimethyl-1,10-phenanthroline)2][tris(4-hydroxyphenyl)ethane^(1-))](CAS DataBase Reference)
• NIST Chemistry Reference: [Cu(2,9-dimethyl-1,10-phenanthroline)2][tris(4-hydroxyphenyl)ethane^(1-))](916657-16-4)
• EPA Substance Registry System: [Cu(2,9-dimethyl-1,10-phenanthroline)2][tris(4-hydroxyphenyl)ethane^(1-))](916657-16-4)

Safety Data

• Hazardous Substances Data: 916657-16-4(Hazardous Substances Data)

Upstream product

• 484-11-7 2.9-dimethyl-1,10-phenanthroline 
• 27955-94-8 1,1,1-tris(4-hydroxyphenyl)ethane 
• 20427-59-2 copper hydroxide 

Relevant articles and documents

Effect of the environment on molecular properties: Synthesis, structure, and photoluminescence of Cu(I) bis(2,9-dimethyl-1,10-phenanthroline) nanoclusters in eight different supramolecular frameworks

By selection of different charge-balancing anionic frameworks and different host-to-guest ratios, the photosensitizer-dye cation [Cu(dmp)2] + (dmp = 2,9-dimethyl-1,10-phenanthroline) has been embedded in a series of three-dimensional host structures. It occurs with variable geometry in different states of aggregation, including weakly interacting monomers, isolated dimers, columns, and layers. A large variation in its emission lifetime is correlated with the relative energy level spacings of the guest- and host-framework components. In a fully saturated host framework, the lifetime exceeds values reported for a series of conventional Cu(dmp)2 salts.