91667-38-8Relevant academic research and scientific papers
The insertion of arynes into the O-H bond of aliphatic carboxylic acids
Wen, Chunxiao,Chen, Qian,He, Zhenwen,Yan, Xinxing,Zhang, Changyuan,Du, Zhiyun,Zhang, Kun
supporting information, p. 5470 - 5473 (2015/09/15)
The insertion of arynes into the O-H bond of aliphatic carboxylic acids promoted by sodium carboxylates is described. The reactions led to the formation of aryl carboxylates in good yields with good chemoselectivities under mild conditions.
CHELATES FROM THE REACTIONS OF CARBOXYLIC ACIDS WITH 3,4-XYLENOL IN THE PRESENCE OF BORON TRIFLUORIDE ETHER COMPLEX
Starkov, S. P.,Panasenko, A. I.,Volkotrub, M. N.,Zhidkova, L. A.
, p. 288 - 289 (2007/10/02)
Reactions of 3,4-xylenol with acetic, propionic, butyric, valeric, phenylacetic, and benzoic acids catalyzed by boron trifluoride ether complex give hitherto unknown BF2-containing chelates, which are converted into the corresponding ketones when heated with aqueous ethanol.The chelates and ketones were characterized by spectral data.
