916750-94-2Relevant academic research and scientific papers
Stereocontrol of palladium(ii)-catalysed aza-Claisen rearrangements using a combination of 1,3-allylic strain and a solvent mediated directing effect
Swift, Michael D.,Sutherland, Andrew
, p. 3889 - 3891 (2008/09/18)
A non-coordination solvent was used for the aza-Claisen rearrangement of δ,ε-disubstituted acetimidates that generates a substrate directing effect, providing excellent stereoselectivity. The aza-Claisen rearrangement of allylic trichloroacetimidates was
