916773-71-2Relevant academic research and scientific papers
One-pot synthesis of ultra-branched mixed tetradentate tripodal phosphines and phosphine chalcogenides
Gusarova, Nina K.,Kuimov, Vladimir A.,Malysheva, Svetlana F.,Belogorlova, Nataliya A.,Albanov, Alexander I.,Trofimov, Boris A.
, p. 9218 - 9225 (2012/11/07)
Ultra-branched mixed tetradentate tripodal phosphines and phosphine chalcogenides have been synthesized by the exhaustive regioselective addition of secondary phosphines, phosphine sulfides and phosphine selenides to available tris(4-vinylbenzyl)phosphine oxide under free-radical conditions (UV irradiation or AIBN) in good to excellent yields.
Reactions of elemental phosphorus and phosphine with electrophiles in superbasic systems: XX. Phosphorylation of 4-vinylbenzyl chloride with elemental phosphorus
Malysheva,Kuimov,Gusarova,Sukhov,Smetannikov,Tarasova,Trofimov
, p. 1880 - 1886 (2008/09/18)
4-Vinylbenzyl chloride reacts with white and red phosphorus, as well as with nanostructured "activated" red phosphorus (complex organophosphorus polymer prepared from white phosphorus under ionizing radiation) in the system concentrated aqueous KOH-dioxan
