916981-72-1Relevant academic research and scientific papers
Hydrothermal syntheses, crystal structures, and photophysical properties of two coordination polymers with mixed ligands
Yan, Li,Liu, Chun-Ling
, p. 119 - 125 (2017/06/06)
Two novel metal-organic coordination polymers [Cd(ipdt)(m-BDC)·3H2O]n (1) and [Pb(mip)2(NTC) ·2H2O]n (2) [ipdt = 2,6-Dimethoxy-4-(1H-1,3,7,8-tetraaza-cyclopenta[l]phenanthren-2-yl)-phenol, mip = 2-(3-
Hydrogen bonded supra-molecular framework in inorganic-organic hybrid compounds: Syntheses, structures, and photoluminescent properties
Yan, Li,Liu, Wei,Li, Chuanbi,Wang, Yifei,Ma, Li,Dong, Qinqin
, p. 240 - 246 (2013/03/28)
Two novel compounds constructed from aromatic acid and N-Heterocyclic ligands have been synthesized by hydrothermal reaction: [Cd(mip)(1,8-NDC)(H 2O)]2 (1) [mip = 2-(3-methoxyphenyl)-1H-imidazo[4,5-f][1, 10]phenanthroline, 1,8-NDC = naphthalene-1,8-dicarboxylic acid] and Cd(mip) 2(NTC)2 (2) [NTC = nicotinic acid]. Compounds 1 and 2 are characterized by elemental analysis, IR, single crystal X-ray diffraction and thermogravimetric analysis (TGA). Single-crystal X-ray investigation reveals that compounds 1-2 are 0 dimensional (0D) structures, and the existence of hydrogen bonds and π-π interactions lead the 0D to 2D novel framework. Hydrogen bonds and π-π interactions are powerful non-covalent intermolecular interactions for directing supra-molecular architectures. TG analysis shows clear courses of weight loss, which corresponds to the decomposition of different ligands. At room temperature, compound 1 exhibits emission at 449 nm upon excitation at 325 nm, and compound 2 shows a strong emission at 656 nm upon excitation at 350 nm. Fluorescent spectrum displays that compounds 1 and 2 are potential luminescent materials.
Syntheses, crystal structures, and photophysical properties of two 2-D coordination polymers
Yan, Li,Li, Chuan-Bi
, p. 4288 - 4298 (2013/02/25)
Two coordination polymers, [Mn(dipt)(m-BDC)3]n (1) and [Pb(mip)(1,4-NDC)]n (2) [dipt=2-(2,4-dichlorophenyl)-1H- imidazo[4,5-f][1,10]phenanthroline, mip=2-(3-methoxyphenyl)- 1H-imidazo[4,5-f][1,10]phenanthroline, m-BDC=isop
