916983-58-9

Upstream product

• 37682-29-4 2-nitrophenyl octyl ether 
• 916983-56-7 4-iodo-2-nitro-1-octyloxy-benzene 
• 916983-57-8 1-(3-nitro-4-octyloxy-phenyl)-1H-imidazole 

Downstream Products

• 916983-59-0 N,N-diethyl-N'-{5-[5-(5-imidazol-1-yl-2-octyloxy-phenylcarbamoyl)-2,4-bis-octyloxy-phenylcarbamoyl]-2,4-bis-octyloxy-phenyl}-malonamide 

Relevant academic research and scientific papers

Foldamer-based pyridine-fullerene tweezer receptors for enhanced binding of zinc porphyrin

This paper reports the design and synthesis of a new series of hydrogen bonding-mediated foldamer-derived tweezer receptors that are used for efficient complexation of zinc porphyrin guest. One end of the rigidified aromatic amide backbone is incorporated with one fullerene unit, while another end is connected to one pyridine or imidazole unit. The 1H NMR, UV-vis, and fluorescent investigations in chloroform revealed that, due to the intramolecular hydrogen bonding-driven preorganized folded conformation, the fullerene and pyridine units of the receptors are located with suitable spatial separation and consequently able to co-complex zinc porphyrin with remarkably increased stability. In contrast, the imidazole-incorporated receptor displays a weakened binding affinity possibly due to structural mismatching and large steric hindrance. The association constants of the complexes of the new receptors with zinc porphyrin have been determined.