91735-53-4

Basic information

• Product Name: Methanone, [2,4-bis(phenylmethoxy)phenyl][3-(2,4,5-trimethoxyphenyl)oxiranyl]-
• CAS NO: 91735-53-4
• Molecular Formula: C32H30O7
• Molecular Weight: 526.586
• Mol File: 91735-53-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Methanone, [2,4-bis(phenylmethoxy)phenyl][3-(2,4,5-trimethoxyphenyl)oxiranyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanone, [2,4-bis(phenylmethoxy)phenyl][3-(2,4,5-trimethoxyphenyl)oxiranyl]-(91735-53-4)
• EPA Substance Registry System: Methanone, [2,4-bis(phenylmethoxy)phenyl][3-(2,4,5-trimethoxyphenyl)oxiranyl]-(91735-53-4)

Safety Data

• Hazardous Substances Data: 91735-53-4(Hazardous Substances Data)

Upstream product

• 91735-52-3 2',4'-Dibenzyloxy-2,4,5-trimethoxychalcone 
• 91735-51-2 4'-Benzyloxy-2'-hydroxy-2,4,5-trimethoxychalcone 
• 4460-86-0 asaraldehyde 
• 29682-12-0 1-[4-(benzyloxy)-2-hydroxyphenyl]ethanone 

Downstream Products

• 75425-27-3 2',4',5'-trimethoxy-6'',6''-dimethylpyrano(2'',3'':7,8)isoflavone 
• 29096-94-4 7-hydroxy-3-(2,4,5-trimethoxyphenyl)-4H-chromen-4-one 

Relevant articles and documents

Synthesis of Barbigerone, a Naturally Occurring Pyranoisoflavone

4'-Benzyloxy-2'-hydroxy-2,4,5-trimethoxychalcone (III) on benzylation gives 2',4'-dibenzyloxy-2,4,5-trimethoxychalcone (IV), which on epoxidation furnishes the corresponding epoxide (V).The latter on rearrangement with BF3-etherate gives 7-hydroxy-2',4',5'-trimethoxyisoflavone (II), via α-formyldesoxybenzoin (VI).II on reaction with 2-methyl-2-chlorobut-3-yne furnishes barbigerone (I), identical with a natural sample.