917358-86-2

Upstream product

• 917358-72-6 3-O-allyl-1,2-O-isopropylidene-α-D-glucofuranose 
• 152185-56-3 3-O-Allyl-1,2-O-isopropylidene-α-D-xylo-pentodialdose 
• 917358-82-8 2,4-di-O-acetyl-3-O-allyl-5,6-dideoxy-1-O-(4-methoxybenzyl)-1-C-phenyl-hex-5-enitol 
• 917358-75-9 1,2-O-(1-methylethylidene)-5-O-(4-methoxybenzyl)-3-O-allyl-5-C-phenyl-5-O-α-D-xylo-furanose 
• 917358-80-6 3-O-allyl-5,6-dideoxy-1-O-(4-methoxybenzyl)-1-C-phenyl-hex-5-enitol 
• 917358-74-8 (R)-((3aR,5R,6S,6aR)-6-allyloxy-2,2-dimethyl-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl)(phenyl)methanol 
• 917358-84-0 2,4-di-O-acetyl-3-O-allyl-5,6-dideoxy-1-C-phenyl-hex-5-enitol 
• 108-24-7 acetic anhydride 

Downstream Products

• 917358-88-4 1,2,4-tri-O-acetyl-3,7-anhydro-5,6-dideoxy-1-C-phenyl-hept-5-enitol 

Relevant academic research and scientific papers

RCM/PCC oxidation strategy for synthesis of functionalized cyclic α,β-unsaturated lactones: synthesis of (+)-triacetoxygoniotriol and its diastereomers

A novel methodology leading to the synthesis of (+)-triacetoxygoniotriol 2 from d-glucose is described. Construction of the core six-membered α,β-unsaturated lactone moiety involved ring closing metathesis (RCM) followed by a PCC oxidation. Later exploiti