91738-18-0Relevant articles and documents
Reactions of Enolic Sugar Derivatives, XVI. - Synthesis of a Diastereotopic Proton Probe for α- and β-D-Glucosylases
Brewer, Curtis F.,Hehre, Edward J.,Lehmann, Jochen,Weiser, Wolfgang
, p. 1078 - 1087 (2007/10/02)
For the elucidation of the stereochemistry in glucosylase-catalyzed proton addition reactions (Z)-3,7-anhydro-1,2-dideoxy-D-gluco-oct-2-enitol (1) was synthesized.Starting material for the multistep synthesis is 3,4,5,7-tetra-O-acetyl-2,6-anhydro-1-C-(1,3
DIASTEREOTOPIC SUBSTRATES OF β-D-GALACTOSIDASE FROM Escherichia coli AS PROBES FOR A CATALYTICALLY ACTIVE, PROTONATING GROUP
Fritz, Hans,Lehmann, Jochen,Schlesselmann, Peter
, p. 71 - 92 (2007/10/02)
With 3,4,5,7-tetra-O-acetyl-2,6-anhydro-D-glycero-L-manno-heptonitrile as the starting material, the diastereotopic, enolic sugar derivatives (Z)-3,7-anhydro-2-deoxy-D-galacto-oct -2-enononitrile (2) and (Z)- (5) and (E)-3,7-anhydro-1,2-dideoxy-D-galacto-