917511-90-1

Basic information

• Product Name: 1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride
• Synonyms: Dichloro[1,1'-bis(dicyclohexylphosphino)ferrocene]palladium (II);Dichloro[1,1'-bis(dicyclohexylphosphino)ferrocene]palladiuM(II), dichloroMethane adduct,98%;[1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladiuM(II);Dichloro[1,1'-bis(dicyclohexylphosphiNA)ferrocene]palladiuM (II);Dichloro [1,1'-bis(dicyclohexy;PalladiuM, [1,1'-bis(dicyclohexylphosphino-κP)ferrocene]dichloro-, (SP-4-2)-;PdCl2(dcypf);1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride
• CAS NO: 917511-90-1
• Molecular Formula: C₃₄H₅₂Cl₂FeP₂Pd
• Molecular Weight: 755.904
• Product Categories: NULL;Pd
• Mol File: 917511-90-1.mol
• Article Data: 1

Chemical Properties

• Melting Point: 294-300 °C
• Appearance: red-orange microcrystal/
• Storage Temp.: ?20°C
• CAS DataBase Reference: 1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride(917511-90-1)
• EPA Substance Registry System: 1,1μ-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride(917511-90-1)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 917511-90-1(Hazardous Substances Data)

Usage

Uses

Different sources of media describe the Uses of 917511-90-1 differently. You can refer to the following data:
1. 1,1'-Bis(di-cyclohexylphosphino)ferrocene palladium dichloride is an air-stable catalyst useful in the arylation of various ketones with aryl chlorides and aryl bromides.
2. 1,1′-Bis(di-cyclohexylphosphino)ferrocene]dichloropalladium(II) or (Pd(dcpf)Cl2) can be used as a catalyst in the synthesis of: α, β-unsaturated amides by hydroaminocarbonylation of alkynes with tertiary amines.Quinazoline derivatives via Suzuki-Miyaura coupling reaction between of quinazolines containing unprotected NH2 group and arylboronic acids. α-aryl carbonyl compounds by α-arylation of ketones with aryl chlorides and aryl bromides.

Upstream product

• 15617-18-2 bis(benzonitrile)palladium(II) dichloride 
• 146960-90-9 1,1'-bis(dicyclohexylphosphinocyclopentadienyl)iron 

Relevant articles and documents

Synthesis and electrochemistry of late transition metal complexes containing 1,1′-bis(dicyclohexylphosphino)ferrocene (dcpf). The X-ray structure of [PdCl2(dcpf)] and Buchwald-Hartwig catalysis using [PdCl2(bisphosphinometallocene)] precursors

The electrochemistry of 1,1′-bis(dicyclohexylylphosphino)ferrocene (dcpf) was examined in methylene chloride with tetrabutylammonium hexafluorophosphate or tetrabutylammonium tetrakis(pentafluorophenyl)borate as the supporting electrolyte. The oxidation of dcpf is complicated by a follow-up reaction. Seven new complexes containing dcpf and one new compound containing 1,1′-bis(di-tert-butylphosphino)ferrocene (dtbpf) were prepared and characterized. The new complexes were analyzed by cyclic voltammetry and the oxidation of these complexes occurred at a more positive potential than the free ligand. In addition, the X-ray structure of [PdCl2(dcpf)] was determined and compared to other palladium complexes containing bisphosphinometallocene ligands. Five different palladium complexes containing bisphosphinometallocene ligands were examined as catalyst precursors in Buchwald-Hartwig catalysis.