91788-49-7Relevant academic research and scientific papers
Iminyl radicals: Part II. Ring opening of cyclobutyl- and cyclopentyliminyl radicals
Boivin, Jean,Fouquet, Eric,Zard, Samir Z.
, p. 1757 - 1768 (2007/10/02)
Slow addition of tributylstannane to sulphenylimines 2 give the corresponding cycloiminyl radicals 3 which can undergo ring opening, a process that is easily incorporated into complex reaction sequences.
Reduction of Oximes and Aliphatic Nitro Compounds to Imines for Further in situ Reactions: A Novel Synthesis of Pyrroles and Pyrrolin-2-ones
Barton, Derek H. R.,Motherwell, William B.,Simon, Ethan S.,Zard, Samir Z.
, p. 2243 - 2252 (2007/10/02)
Tributhylphosphine-diphenyl disulphide is a self-drying reagent capable of reducing ketoximes and secondary aliphatic nitro compounds to the corresponding imines under strictly anhydrous conditions at room temperature.The imine may be hydrolysed to a ketone, acetylated to give an enamide, reduced to an amine , or captured by hydrogen cyanide to produce an α-amino nitrile.In the case of 1,4-nitro ketones or esters, intramolecular cyclisation leads to pyrroles or pyrrolin-2-ones.Aldoximes and primary nitro compounds are converted into nitriles by the reagent.Hydroxamic acids are reduced to the corresponding amides.
A Mild and Efficient Method for the Reduction of Oximes to Imines for Further in situ Reactions
Barton, Derek H. R.,Motherwell, William B.,Simon, Ethan S.,Zard, Samir Z.
, p. 337 - 338 (2007/10/02)
Tributylphosphine-diphenyl disulphide is an effective and mild reagent for reducing oximes to imines.
