918335-72-5Relevant academic research and scientific papers
C-H versus O-H bond cleavage reactions of Bis(2-hydroxyphenyl)phenylamine, PhN(o-C6H4OH)2: Synthesis and structural characterization of mononuclear and dinuclear tungsten aryloxide complexes which exhibit bidentate, tridentate, and tetradentate coordination modes
Kelly, Bryte V.,Tanski, Joseph M.,Janak, Kevin E.,Parkin, Gerard
, p. 5839 - 5842 (2008/10/09)
The phenylimino-bridged diphenol PhN(o-C6H4OH) 2 reacts with W(PMe3)4(η2- CH2PMe2)H to yield a variety of mononuclear and dinuclear complexes that include [κ2-PhN(C6H 4-OH)(C6H3O)]W(PMe3) 4H2, [μ-κ2,κ2- PhN(C6H3O)2]{W-(PMe3) 4H2}2, [κ3-PhN(C 6H4O)2]W(PMe3)3H 2, [κ4-N(C6H4)-(C 6H4O)2]W(PMe3)3H, and [κ2-PhN(C6H4O)2] 2W(PMe3)2 via O-H and C-H bond activation reactions. Structural characterization of these compounds by X-ray diffraction demonstrates that the derived alkoxide ligand is structurally flexible and can adopt bidentate, tridentate, and tetradentate coordination modes.
