918404-00-9Relevant academic research and scientific papers
γ-chloromagnesio γ-lactones and δ-chloromagnesio γ-lactones: Generation, properties, and synthetic uses
Shimizu, Hitomi,Fukuda, Shigehiko,Sugiyama, Shimpei,Satoh, Tsuyoshi
experimental part, p. 1323 - 1335 (2009/12/07)
Treatment of γ- and δ-lactones having a sulfinyl group at the γ- and δ-positions with isopropylmagnesium chloride in THF at -78°C gave γ-chloromagnesio γ-lactones and δ- chloromagnesio δ-lactones, respectively, by the sulfoxide-magnesium exchange reaction
The first example of γ-chloromagnesio γ-lactones: their generation from γ-tolylsulfinyl γ-lactones with isopropylmagnesium chloride, stability, and reaction with electrophiles
Sugiyama, Shimpei,Shimizu, Hitomi,Satoh, Tsuyoshi
, p. 8771 - 8775 (2007/10/03)
The treatment of γ-lactones having a sulfinyl group at the γ-position, which were synthesized from 1-chlorovinyl p-tolyl sulfoxides with lithium enolate of carboxylic esters, with isopropyl magnesium chloride in THF at -78 °C gave γ-chloromagnesio γ-lacto
