918445-78-0Relevant articles and documents
Markovnikov versus anti-Markovnikov selectivity in the amination of terminal olefins coordinated to platinum(II)
Lorusso, Giuseppe,Di Masi, Nicola G.,Maresca, Luciana,Pacifico, Concetta,Natile, Giovanni
, p. 500 - 503 (2006)
The products of addition of secondary amines to platinum(II)-coordinated terminal olefins undergo a fast Markovnikov (M)-anti-Markovnikov (anti-M) isomerization process leading, to an equilibrium composition different from that obtained under kinetic control; in basic medium, the amination products undergo intramolecular ring closing reaction which is faster for the anti-M isomers, so decreasing the M/anti-M ratio in the final complexes.