918477-28-8Relevant articles and documents
Doubly degradable dynamers: Dynamic covalent polymers based on reversible imine connections and biodegradable polyester units
Fukuda, Kazuyuki,Nobori, Tadahito,Lehn, Jean-Marie,Shimoda, Manabu,Sukegawa, Makoto
, p. 2907 - 2911,5 (2012)
We report the preparation and features of environmentally friendly Green Dynamers (GDs), dynamic polymers presenting sequential double-degradation features, chemical and biological. They were obtained by connecting biodegradable oligomers (such as small units of polybutylene adipate, PBA, and polybutylene succinate, PBS) through chemically degradable reversible imine bonds. The GDs possess water disintegratability, mendability and biodegradability. Their degradation rate may be modulated through and increases with the number of imine groups in the polymeric chain. The GDs were thermodynamically stable and maintained their molecular weight and their mechanical strength in air. However, when they were contacted with water, the imine bonds easily hydrolyzed, breaking up the polymer chains into oligomers. After such water disintegration, the residual oligomers were biodegraded into CO2 and water. In addition, the imine bonds were restored by evaporation of the water, leading to recovery of the molecular weight and of the mechanical properties of the GDs. The present GDs may be considered to represent a class of doubly-degradable polymers, combining chemical and biological degradability features, that operate in mild environmental conditions. This concept may contribute to solve the problem of waste elimination associated with the use of non-degradable polymeric materials.
