91859-98-2Relevant articles and documents
Access to a Chiral Phosphine-NHC Palladium(II) Complex via the Asymmetric Hydrophosphination of Achiral Vinyl Azoles
Leung, Pak-Hing,Li, Yongxin,Pullarkat, Sumod A.,Seah, Jeffery Wee Kiong
, p. 2118 - 2122 (2021)
Enantioenriched phosphine azoles were synthesized in high yields via palladium-catalyzed asymmetric hydrophosphination with excellent yields and enantioselectivities under mild reaction conditions. One of the phosphine azoles was methylated and complexed to palladium(II) cleanly to give a chiral phosphine-NHC palladium(II) complex with excellent overall conversion.