91860-91-2Relevant academic research and scientific papers
Chelation-Controlled Facially Selective Cyclocondensation Reactions of Chiral Alkoxy Aldehydes: Syntheses of a Mouse Androgen and of a Carbon-Linked Disaccharide
Danishefsky, Samuel J.,Pearson, William H.,Harvey, Daniel F.,Maring, Clarence J.,Springer, James P.
, p. 1256 - 1268 (2007/10/02)
Magnesium bromide in tetrahydrofuran catalyzes the cycloaddition of a variety of chiral alkoxy aldehydes with activated butadienes.The stereochemistry of these products is such that they can be rationalized as arising from a reacting conformer in which th
