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Ligand Scrambling in Bismuth(III) Dithiocarbamates
Soundararajan, G.,Subbaiyan, M.
, p. 1182 - 1185 (2007/10/02)
Dithiocarbamate moieties are found to be labile in bismuth(III) dithiocarbamates as in other metal dithiocarbamates.Unsymmetric mixed ligand dithiocarbamates are formed by ligand scrambling while mixing simple symmetrical dithiocarbamates in non-polar solvents.Elemental analyses, electronic, ir and nmr spectral studies showed that these complexes are identical with those derived from halo bisdithiocarbamates.
