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1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium(II)dichloride, also known as Zhan Catalyst-1B, is a Hoveyda-Grubbs type catalyst with unique structural features that enhance its catalytic activity in various chemical reactions.

918870-76-5

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918870-76-5 Usage

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Used in Preparation of Hybrid Olefin Metathesis Catalysts:
1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium(II)dichloride is used as a catalyst precursor for the preparation of hybrid olefin metathesis catalysts, which exhibit increased catalytic activity due to immobilization on molecular sieves or other supports.
Used in Synthesis of Divergent Dendrimers:
In the field of dendrimer chemistry, 1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium(II)dichloride serves as a catalyst in the synthesis of divergent dendrimers, enabling the construction of complex and highly branched molecular architectures with potential applications in various fields, such as drug delivery, sensing, and nanotechnology.
Used in Ring-Closure Metathesis (RCM) Reactions:
1,3-Bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(i-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methyleneruthenium(II)dichloride is utilized as a catalyst in ring-closure metathesis (RCM) reactions, a powerful method for the formation of cyclic olefins from dienes. This catalyst plays a crucial role in the synthesis of various cyclic compounds, including pharmaceuticals, agrochemicals, and advanced materials.

Check Digit Verification of cas no

The CAS Registry Mumber 918870-76-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 9,1,8,8,7 and 0 respectively; the second part has 2 digits, 7 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 918870-76:
(8*9)+(7*1)+(6*8)+(5*8)+(4*7)+(3*0)+(2*7)+(1*6)=215
215 % 10 = 5
So 918870-76-5 is a valid CAS Registry Number.

918870-76-5 Well-known Company Product Price

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  • Aldrich

  • (762261)  Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][[5-[(dimethylamino)sulfonyl]-2-(1-methylethoxy-O)phenyl]methylene-C]ruthenium(II)  

  • 918870-76-5

  • 762261-100MG

  • 496.08CNY

  • Detail
  • Aldrich

  • (762261)  Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][[5-[(dimethylamino)sulfonyl]-2-(1-methylethoxy-O)phenyl]methylene-C]ruthenium(II)  

  • 918870-76-5

  • 762261-500MG

  • 1,990.17CNY

  • Detail
  • Aldrich

  • (762261)  Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene][[5-[(dimethylamino)sulfonyl]-2-(1-methylethoxy-O)phenyl]methylene-C]ruthenium(II)  

  • 918870-76-5

  • 762261-2G

  • 6,341.40CNY

  • Detail

918870-76-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name Dichloro(1,3-dimesityl-2-imidazolidinylidene)[5-(dimethylsulfamoy l)-2-isopropoxybenzylidene]ruthenium

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

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Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:918870-76-5 SDS

918870-76-5Upstream product

918870-76-5Downstream Products

918870-76-5Relevant academic research and scientific papers

Ruthenium complex, preparation method and application thereof

-

Paragraph 0153-0157; 0160-0165; 0169, (2019/01/23)

The invention discloses a ruthenium complex, a preparation method and application thereof. The ruthenium complex disclosed in the invention is as shown in formula I. The ruthenium complex has good catalytic activity and stereoselectivity, provides various optimization options for catalytic cyclization of various olefin raw materials, can be used for industrial production of a catalyst for variousolefin metathesis translocation decomposition, and has a good application value.

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