91890-06-1

Basic information

• Product Name: 2-Hexanone, 4-hydroxy-3-methyl-, (R*,S*)- (9CI)
• Synonyms: 2-Hexanone, 4-hydroxy-3-methyl-, (R*,S*)- (9CI)
• CAS NO: 91890-06-1
• Molecular Formula: C7H14O2
• Molecular Weight: 130.18486
• Product Categories: ACETYLGROUP
• Mol File: 91890-06-1.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Hexanone, 4-hydroxy-3-methyl-, (R*,S*)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Hexanone, 4-hydroxy-3-methyl-, (R*,S*)- (9CI)(91890-06-1)
• EPA Substance Registry System: 2-Hexanone, 4-hydroxy-3-methyl-, (R*,S*)- (9CI)(91890-06-1)

Safety Data

• Hazardous Substances Data: 91890-06-1(Hazardous Substances Data)

Upstream product

• 97231-17-9 4,4,5,5-tetramethyl-2-<(E)-1-methyl-1-propenyloxy>-1,3,2-dioxaborolane 
• 123-38-6 propionaldehyde 
• 91890-01-6 4,4,5,5-tetramethyl-2-<(Z)-1-methyl-1-propenyloxy>-1,3,2-dioxoborolane 
• 73255-30-8 (+/-)-3-(1-hydroxypropyl)but-3-en-2-one 
• 80719-79-5 2,3-Dimethyl-3-butenal 
• 925-90-6 ethylmagnesium bromide 

Relevant articles and documents

Rhodium(I)- or ruthenium(II)-catalyzed direct coupling of vinyl ketones with aldehydes and the subsequent reduction to give aldol derivatives anti-selectively

A vinyl ketone reacts with an aldehyde to give an α-methylene-β-hydroxyalkanone with the concomitant formation of the vinyl ketone dimer in the presence of catalytic amount of RhH(PPh3)4 or RuH2(PPh3)4 under almost neutral conditions.The selectivity of th

SYN-SELECTIVE ADDITION OF ENOL BORATES TO ALDEHYDES

Both the Z- and the E-enolborate 4 and 6 add to aldehydes in a stereoconvergent reaction to give β-hydroxyketones with a syn/anti ratio of >= 9 : 1.