91902-46-4Relevant academic research and scientific papers
Reaction of arynes with sulfoxides
Li, Hong-Ying,Xing, Li-Juan,Lou, Mei-Mei,Wang, Han,Liu, Rui-Hua,Wang, Bin
, p. 1098 - 1101 (2015/03/14)
A S-O bond insertion reaction of sulfoxides with arynes is reported. This reaction represents a rare instance of semipolar single bond insertion in aryne chemistry. The study of mechanism indicates that a sulfur ylide triggered by aryne is the key intermediate, which further transfers its methylene group to carbonyl compounds to give epoxides and thioethers through a sequential process.
