919096-70-1Relevant articles and documents
A general strategy for synthesis of both (6Z)- and (6E)-cladiellin diterpenes: Total syntheses of (-)-cladiella-6,11-dien-3-ol, (+)-polyanthellin A, (-)-cladiell-11-ene-3,6,7-triol, and (-)-deacetoxyalcyonin acetate
Kim, Hyoungsu,Lee, Hyunjoo,Kim, Jayoung,Kim, Sanghee,Kim, Deukjoon
, p. 15851 - 15855 (2006)
The first total synthesis of an (E)-cladiellin diterpene, (-)-cladiella-6,11-diene-3-ol (1), was accomplished featuring an intramolecular amide enolate alkylation-intramolecular Diels-Alder strategy. In addition, a highly stereo-, regio-, and chemoselecti