919110-85-3Relevant academic research and scientific papers
Total synthesis of the proposed structure of the anthrapyran metabolite δ-indomycinone
Tietze, Lutz F.,Singidi, Ramakrishna Reddy,Gericke, Kersten M.
, p. 9939 - 9947 (2008/09/18)
The first total synthesis of the proposed structure of δ-indomycinone has been accomplished. The key steps involve the Diels-Alder reaction of a bromonaphthoquinone (6) and 1-methoxy-3-methyl-1-trimethylsiloxy-1,3-butadiene (7) to access the anthraquinone
First enantioselective total synthesis and structure determination of the anthrapyran metabolite γ-indomycinone
Tietze, Lutz F.,Singidi, Ramakrishna Reddy,Gericke, Kersten M.
, p. 5873 - 5876 (2007/10/03)
(Diagram presented) The first total synthesis of (R)-γ-indomycinone has been achieved which allowed the determination of the configuration of the stereogenic center of natural γ-indomycinone as (S). The approach stands out for its generality and efficienc
