919366-83-9Relevant academic research and scientific papers
Iridium-catalysed dehydrocoupling of aryl phosphine-borane adducts: Synthesis and characterisation of high molecular weight poly(phosphinoboranes)
Paul, Ursula S. D.,Braunschweig, Holger,Radius, Udo
, p. 8573 - 8576 (2016)
The thermal dehydrogenative coupling of aryl phosphine-borane adducts with iridium complexes bearing a bis(phosphinite) pincer ligand is reported. This catalysis produces high molecular weight poly(phosphinoboranes) [ArPH-BH2]n (Ar = Ph, pTol, Mes). Furthermore, we investigated the reactivity of these pincer complexes towards primary phosphines and their respective borane adducts on a stoichiometric scale.
