91967-51-0

Basic information

• Product Name: o-isobutylanisole
• Synonyms: o-isobutylanisole;1-Methoxy-2-(2-methylpropyl)benzene;Einecs 295-246-0
• CAS NO: 91967-51-0
• Molecular Formula: C₁₁H₁₆O
• Molecular Weight: 164.24414
• EINECS: 295-246-0
• Mol File: 91967-51-0.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 214.9°Cat760mmHg
• Flash Point: 84.6°C
• Appearance: /
• Density: 0.914g/cm³
• Vapor Pressure: 0.223mmHg at 25°C
• Refractive Index: 1.487
• CAS DataBase Reference: o-isobutylanisole(CAS DataBase Reference)
• NIST Chemistry Reference: o-isobutylanisole(91967-51-0)
• EPA Substance Registry System: o-isobutylanisole(91967-51-0)

Safety Data

• Hazardous Substances Data: 91967-51-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C11H16O/c1-9(2)8-10-6-4-5-7-11(10)12-3/h4-7,9H,8H2,1-3H3

Upstream product

• 6026-72-8 1-(2-methoxyphenyl)-2-methylprop-1-ene 
• 578-57-4 2-bromoanisole 
• 677-22-5 tert-butylmagnesium chloride 
• 135-02-4 ortho-anisaldehyde 
• 6642-39-3 1-(2-methoxy-phenyl)-2-methyl-propan-1-ol 
• 4416-67-5 2-tosyloxyanisole 
• 5674-02-2 2-methylpropylmagnesium chloride 
• 64-17-5 ethanol 
• 120958-26-1 (E)-3-(2-methoxyphenyl)-2-methylacrylaldehyde 
• 1779-25-5 diisobutylaluminum chloride 
• 31600-86-9 2-methoxyphenyllithium 
• 91969-32-3 1-methoxy-2-(2-methylallyl)benzene 

Downstream Products

• 475272-03-8 4-iodo-2-isobutylanisole 
• 4167-75-3 2-isobutylphenol 

Relevant articles and documents

Zn-Mediated Hydrodeoxygenation of Tertiary Alkyl Oxalates

Herein we describe a general, mild, and scalable method for hydrodeoxygenation of readily accessible tertiary alkyl oxalates by Zn/silane under Ni-catalyzed conditions. The reduction method is suitable for an array of structural motifs derived from tertiary alcohols that bear diverse functional groups, including the synthesis of a key intermediate en route to estrone.

Kumada coupling of aryl and vinyl tosylates under mild conditions

Aryl and alkenyl tosylates are easily prepared, inexpensive and, thus, attractive for transition-metal-catalyzed couplings, but their reactivity is low. We report examples of mild, palladium-catalyzed coupling of aryl, alkenyl, and alkyl Grignard reagents with aryl and alkenyl tosylates. The resulting biaryls, vinylarenes, and alkylarenes were isolated in good to excellent yield. These couplings were conducted with a nearly equimolar ratio of the two reactants, and many examples were conducted at room temperature.

A novel oxovanadium(V)-induced oxidation of organoaluminum compounds. Highly selective coupling of organic substituents on aluminum [7]

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