919765-94-9Relevant academic research and scientific papers
A synthetic cycle for the ruthenium-promoted formation of 1H-phosphindoles from phosphaalkynes
Cordaro, Joseph G.,Stein, Daniel,Gruetzmacher, Hansjoerg
, p. 14962 - 14971 (2008/02/04)
Beginning with inexpensive and commercially available starting materials, a rational synthesis for the new phosphaalkyne Ph3C-C≡P (1) is presented. Coordination of 1 to group 8 transition metal centers furnishes the η1-complexes [MH(
