919990-61-7

Basic information

• Product Name: trans-[PdCl₂(2,3,4-trifluoroaniline)2]
• CAS NO: 919990-61-7
• Molecular Weight: 471.525
• Mol File: 919990-61-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-[PdCl₂(2,3,4-trifluoroaniline)2](CAS DataBase Reference)
• NIST Chemistry Reference: trans-[PdCl₂(2,3,4-trifluoroaniline)2](919990-61-7)
• EPA Substance Registry System: trans-[PdCl₂(2,3,4-trifluoroaniline)2](919990-61-7)

Safety Data

• Hazardous Substances Data: 919990-61-7(Hazardous Substances Data)

Upstream product

• 14220-64-5 bis(benzonitrile)palladium(II) chloride 
• 3862-73-5 2,3,4-trifluoroaniline 

Relevant articles and documents

Phosphane-free C-C Heck couplings catalyzed by Pd(II) fluorinated aniline complexes of the type trans-[PdCl2(NH2ArF) 2]

A series of palladium fluoro-aniline complexes of the trans-[PdCl 2(NH2ArF)2] type were synthesized in good yields by direct reaction of trans-[PdCl2(C6H 5CN)] with ArFNH2; ArF = C 6H3-2,3-F2 (1), C6H 3-2,5-F2 (2), C6H3-3,4-F2 (3), C6H3-3,5-F2 (4), C6H 2-2,3,4-F3 (5), C6H2-2,3,6-F 3 (6), C6H2-2,4,5-F3 (7), C 6H2-2,4,6-F3 (8), C6F 4-4-H (9), C6F5 (10). The crystal structures of complexes 3, 4 and 5 were determined. Heck coupling reactions were carried out using complexes 1-10 as catalysts in order to examine the effect of the fluorinated anilines in the reaction of bromobenzene and styrene.