92012-57-2Relevant academic research and scientific papers
Synthetic protocols, molecular polarity, and13C NMR correlations for 1-aryl- and 1-diarylmethylidene-1H-cyclopropa[b]naphthalenes
Halton, Brian,Dixon, Gareth M.
, p. 3139 - 3149 (2007/10/03)
The Peterson olefination for alkylidenecycloproparene synthesis from a 1,1-disilylcycloproparene has been refined into five distinct protocols that have provided 43 new aryl- (5 and 6) and diaryl- (7 and 8). and aryl(phenyl)- (9 and 10) methylidene deriva
Studies in the cycloproparene series: 1 chemistry of the 1-trimethylsilyl-1H-cyclopropa[b]naphthalenyl anion
Halton, Brian,Jones, Carissa S.
, p. 2505 - 2508 (2007/10/03)
Desilylation of 1,1-bis(trimethylsilyl)-1H-cyclopropa[b]naphthalene 10 with tert-butoxide or hydroxide ion gives anion 9 as a highly reactive species. Formed with tert-butoxide 9 can be intercepted by iodomethane to give the 1-methyl-1-trimethylsilyl deri
Studies in the cycloproparene series: Reactivity of the 1H-cyclopropa[b]naphthalenyl anion
Cutler, Charlotte A.,Halton, Brian
, p. 267 - 270 (2007/10/03)
Proton abstraction from C1 of 1H-cyclopropa[b]naphthalene (1b) provides anion (2b) as a highly reactive species that is difficult to intercept in solution with simple electrophiles. The use of iodomethane, benzophenone and acetone leads to the correspondi
