92015-51-5Relevant academic research and scientific papers
Microwave specific Wolff rearrangement of α-diazoketones and its relevance to the nonthermal and thermal effect
Sudrik, Surendra G.,Chavan, Sambhaji P.,Chandrakumar,Pal, Sourav,Date, Sadgopal K.,Chavan, Subhash P.,Sonawane, Harikisan R.
, p. 1574 - 1579 (2007/10/03)
α-Diazoketones possess high electric dipole moments, as a consequence of the dipolar nature of the diazocarbonyl functional group. The vectorial analysis, theoretical calculations (PM3 and ab initio), and literature reports based on experimental and theor
STRUCTURE AND PROPERTIES OF THE PRODUCTS FROM THERMAL CYCLIZATION OF 1-ACETOXY-3,7-DIMETHYL-1,2,6-OCTATRIENE
Erman, M. B.,Volkova, O. O.,Cherkaev, G. V.,Pribytkova, I. M.,Antipin, M. Yu.,et al.
, p. 2252 - 2261 (2007/10/02)
2-Acetoxymethyl-3-isopropenyl-1-methylcyclopentene, 5-acetoxymethylene-1,6,6-trimethylbicyclohexane, and 2,6,6-trimethyl-exo- and 2,6,6-trimethyl-endo-7-acetoxybicyclohept-1-enes with a double bond at the "bridgehead" were obtained by thermal cyclization of 1-acetoxy-3,7-dimethyl-1,2,6-octatriene.The products are oxidized unusually readily by atmospheric oxygen with the formation of the unsaturated 1-hydroxy derivatives.Hydrolysis of the thermal cyclization products gave the corresponding hydroxy and oxo compounds, and their characteristics were studied.The geometry of the 1-hydroxy-2,6,6-trimethyl-endo-7-acetoxybicyclohept-2-ene molecule was determined by the X-ray crystallographic method.
