92032-30-9Relevant academic research and scientific papers
Room-temperature Cu-catalyzed: N -arylation of aliphatic amines in neat water
Wang, Deping,Zheng, Yanwen,Yang, Min,Zhang, Fuxing,Mao, Fangfang,Yu, Jiangxi,Xia, Xiaohong
, p. 8009 - 8012 (2017)
A room-temperature and PTC-free copper-catalyzed N-arylation of aliphatic amines in neat water has been developed. Using a combination of CuI and 6,7-dihydroquinolin-8(5H)-one oxime as the catalyst and KOH as the base, a wide range of aliphatic amines are arylated with various aryl and heteroaryl halides to give the corresponding products in up to 95% yield.
2-Pyridinyl β-ketones as new ligands for roomerature CuI-catalysed C-N coupling reactions
Wang, Deping,Ding, Ke
supporting information; experimental part, p. 1891 - 1893 (2009/10/23)
2-Pyridinyl β-ketones were identified as new efficient ligands for CuI-catalysed N-arylation of aliphatic amines at room temperature with great selectivity and substrate scope tolerance.
