92037-30-4Relevant academic research and scientific papers
Simple synthetic protocols for tertiary alkyl and allyl thiols
Gurudutt, K. N.,Rao, Sanjay,Srinivas, P.,Srinivas, S.
, p. 1169 - 1171 (2007/10/03)
Convenient preparative methods for tertiary alkyl and allyl thiols are described. Accordingly, thiolesters and thiocyanates, obtained from the reaction of SN1-active halides and appropriate zinc salts, on hydrolysis and LAH reduction respectively, afford the corresponding thiols in near quantitative yields. Besides the well known p-menth-1-ene-8-thiol, p-menthane-1-thiol, p-mentha-1,8-diene-6-thiol and 2-(2-phenyl)propane thiol have been prepared.
