92056-47-8

Upstream product

• 5208-89-9 (E)-1-phenyl-1,4-pentadien-3-ol 
• 79-22-1 methyl chloroformate 

Downstream Products

• 673456-90-1 (+)-(S)-dimethyl [(2E)-3-phenyl-1-vinylprop-2-enyl]malonate 
• 92056-50-3 2-((2E,4E)-5-Phenyl-penta-2,4-dienyl)-malonic acid dimethyl ester 
• 92056-51-4 2-((E)-1-Phenyl-penta-2,4-dienyl)-malonic acid dimethyl ester 
• 92056-49-0 2-((E)-3-Phenyl-1-vinyl-allyl)-malonic acid dimethyl ester 
• 92056-52-5 2-Allyl-2-((2E,4E)-5-phenyl-penta-2,4-dienyl)-malonic acid dimethyl ester 
• 92056-54-7 2-Allyl-2-((E)-1-phenyl-penta-2,4-dienyl)-malonic acid dimethyl ester 
• 92056-53-6 2-Allyl-2-((E)-3-phenyl-1-vinyl-allyl)-malonic acid dimethyl ester 

Relevant academic research and scientific papers

Counteranion-controlled regioselectivity in palladium-catalyzed allylic amination of dienyl allylic carbonates

A regioselective Pd-catalyzed allylic amination reaction of dienyl allylic carbonates and aromatic amines has been developed by means of phosphoramidite-palladium catalysis. The regioselectivity could be altered by the counterion of the π-allylpalladium intermediate. As a result, either branched Z-dienyl allylic amines or linear conjugated allylic amines were generated in high levels of regioselectivity from the same substrates by tuning the reaction conditions.