92056-48-9

Upstream product

• 58927-78-9 (2E,4E)-1-phenyl-2,4-hexadien-1-ol 
• 108-24-7 acetic anhydride 

Downstream Products

• 122800-48-0 acetic acid (2E,4E)-1-methyl-5-phenyl-penta-2,4-dienyl ester 
• 92056-55-8 2-[(E)-1-((E)-Styryl)-but-2-enyl]-malonic acid dimethyl ester 
• 92056-57-0 2-((2E,4E)-1-Methyl-5-phenyl-penta-2,4-dienyl)-malonic acid dimethyl ester 
• 92056-56-9 2-((2E,4E)-1-Phenyl-hexa-2,4-dienyl)-malonic acid dimethyl ester 
• 92056-60-5 2-Allyl-2-((2E,4E)-1-methyl-5-phenyl-penta-2,4-dienyl)-malonic acid dimethyl ester 
• 92056-59-2 2-Allyl-2-((2E,4E)-1-phenyl-hexa-2,4-dienyl)-malonic acid dimethyl ester 
• 92056-58-1 2-Allyl-2-[(E)-1-((E)-styryl)-but-2-enyl]-malonic acid dimethyl ester 

Relevant academic research and scientific papers

Silica gel-mediated rearrangement of allylic acetates. Application to the synthesis of 1,3-enynes

Silica gel was found to efficiently promote the rearrangement of allylic acetates into their most stable regioisomers under microwave irradiation. The reaction is easy to perform and eco-friendly. This method was applied to the metal-free synthesis of 1,3-enynes.