920750-01-2

Upstream product

• 66703-03-5 trans-1-iodo-1-pentene 
• 80434-59-9 (1R,2S,5R)-2-isopropyl-5-methylcyclohexanecarboxaldehyde 
• 868744-83-6 (R,E)-1-((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)hex-2-en-1-ol 
• 103-72-0 phenyl isothiocyanate 

Downstream Products

• 920750-03-4 (1S,2S,4R)-2-((E)-(R)-3-Allylsulfanyl-hex-1-enyl)-1-isopropyl-4-methyl-cyclohexane 
• 920750-06-7 (1S,2S,4R)-1-Isopropyl-4-methyl-2-[(E)-(R)-3-(prop-2-ene-1-sulfonyl)-hex-1-enyl]-cyclohexane 

Relevant academic research and scientific papers

Efficient preparation of chiral non-racemic sulfur compounds

p-Menthane-3-carboxaldehyde serves as an efficient chiral auxiliary in the preparation of chiral non-racemic S-alkylthiocarbamates or 5-dithiocarbonates via the 3,3-sigmatropic rearrangement of the corresponding alkylthionocarbamates or xanthates. The tra

Cleavage of a chiral auxiliary using RCM on an especially sterically crowded alkene: Syntheses of chiral carbo- and heterocycles

Chiral 1,5-, 1,6-, and 1,7-dienes generated in 3-4 steps from chiral auxiliary p-menthane-3-carboxaldehyde undergo RCM with notable discrepancies in reactivity depending on the nature and number of substituents flanking the central double bond. The chiral