920757-99-9

Upstream product

• 920757-82-0 2-(1,1-dimethylallyl)-2-trimethylsiloxyhexanal 

Downstream Products

• 920758-04-9 3-{(S)-2-[(4S,5S)-5-Butyl-5-(1,1-dimethyl-allyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-1-methyl-cyclohex-2-enyl}-propan-1-ol 
• 920758-01-6 (4S,5S)-4-Butyl-4-(1,1-dimethyl-allyl)-5-[(S)-6-(3-hydroxy-propyl)-6-methyl-cyclohex-1-enyl]-[1,3]dioxolan-2-one 
• 920758-05-0 (4S,5S)-5-[(S)-6-allyl-6-methylcyclohex-1-enyl]-4-butyl-4-(1,1-dimethylallyl)-2,2-dimethyl[1,3]dioxolane 
• 920758-02-7 (4S,5S)-5-((S)-6-Allyl-6-methyl-cyclohex-1-enyl)-4-butyl-4-(1,1-dimethyl-allyl)-[1,3]dioxolan-2-one 
• 920758-00-5 (4S,5S)-4-Butyl-4-(1,1-dimethyl-allyl)-5-[(S)-6-methyl-6-(3-trityloxy-propyl)-cyclohex-1-enyl]-[1,3]dioxolan-2-one 
• 920758-03-8 (1S,2S)-2-(1,1-dimethylallyl)-1-[(S)-6-(3-hydroxypropyl)-6-methylcyclohex-1-enyl]hexane-1,2-diol 

Relevant academic research and scientific papers

Synthesis of model BC bicycles of taxol using C10-C11 ring-closing metathesis strategy

Model BC ring-systems of taxol 23b and 28b, which lack an oxygenated substituent at C7, have been efficiently synthesized. The key step is a ring-closing metathesis (RCM) to form the 8-membered B ring between C10 and C11. Comparison of the metathesis reac