920758-38-9Relevant academic research and scientific papers
A tosylimido analogue of a nonheme oxoiron(IV) complex
Klinker, Eric J.,Jackson, Timothy A.,Jensen, Michael P.,Stubna, Audria,Juhasz, Gergely,Bominaar, Emile L.,Muenck, Eckard,Que Jr., Lawrence
, p. 7394 - 7397 (2006)
(Figure Presented) High-valent versatility: N4Py is a versatile pentadentate ligand demonstrated to stabilize both high-valent oxo and imido compounds. The [FeIV(NTs)(N4Py)]2+ complex (see DFT-optimized structure) has been characterized spectroscopically and formulated as having an S=1 iron(IV) center with an Fe=N bond (1.73 A) that is longer than the Fe=O bond of its oxo analogue (1.65 A).
