92085-90-0

Upstream product

• 92085-86-4 (+)-tert-butyl {(1R)-1-[(benzyloxy)methyl]prop-2-en-1-yl}carbamate 
• 23680-31-1 BOC-O-benzyl-L-serine 

Relevant academic research and scientific papers

FunctionaIized erythro N-protected α-amino epoxides. Stereocontrolled synthesis and biological activity

Erythro N-protected α-amino epoxides, derived from α-amino acids bearing functionalized side chains, were synthesized. The key synthetic step is a stereoselective reduction of the corresponding haloketone either to the halohydrin or directly to the epoxid

SYNTHESIS OF (+)-GALANTINIC ACID, A CONSTITUENT AMINO ACID IN THE PEPTIDE ANTIBIOTIC GALANTIN I, via THE STEREOSELECTIVE EPOXIDATION OF A CHIRAL SERINE EQUIVALENT

Epoxidation of (2R)-t-butoxycarbonylamino-3-butenol afforded, in a highly stereoselective manner, a threo-3,4-epoxy-2-aminobutanol derivative which was succesfully converted to the unusual amino acid (+)-galantinic acid in 8 steps via regiospecific epoxide ring opening with divinyl cuprate.