921038-78-0Relevant articles and documents
Synthesis and conformation of multi-vicinal fluoroalkane diastereoisomers
Hunter, Luke,Slawin, Alexandra M. Z.,Kirsch, Peer,O'Hagan, David
, p. 7887 - 7890 (2008/09/18)
(Chemical Equation Presented) Doing the twist: Differences in behavior between isomers of straight-chain alkanes bearing four vicinal fluorine atoms are revealed by conformational analyses (X-ray diffraction, NMR spectroscopy). For example, computational
Enantioselective synthesis of an all-syn four vicinal fluorine motif
Hunter, Luke,O'Hagan, David,Slawin, Alexandra M. Z.
, p. 16422 - 16423 (2007/10/03)
Alkanes bearing multiple vicinal fluorine atoms at adjacent stereocenters may be considered intermediate between alkanes and perfluoroalkanes, and as a class, their chemistry and behavior remain to be explored. We report here a stereoselective synthesis o