92203-17-3Relevant academic research and scientific papers
Biomass chitosan-derived nitrogen-doped carbon modified with iron oxide for the catalytic ammoxidation of aromatic aldehydes to aromatic nitriles
Wang, Wei David,Wang, Fushan,Chang, Youcai,Dong, Zhengping
, (2020/11/24)
Nitrogen-doped carbon catalysts have attracted increasing research attention due to several advantages for catalytic application. Herein, cost-effective, renewable biomass chitosan was used to prepare a N-doped carbon modified with iron oxide catalyst (Fe2O3@NC) for nitrile synthesis. The iron oxide nanoparticles were uniformly wrapped in the N-doped carbon matrix to prevent their aggregation and leaching. Fe2O3@NC-800, which was subjected to carbonization at 800 °C, exhibited excellent activity, selectivity, and stability in the catalytic ammoxidation of aromatic aldehydes to aromatic nitriles. This study may provide a new method for the fabrication of an efficient and cost-effective catalyst system for synthesizing nitriles.
Redox reaction between benzyl azides and aryl azides: concerted synthesis of aryl nitriles and anilines
Kim, Yongjin,Rhee, Young Ho,Park, Jaiwook
supporting information, p. 1636 - 1641 (2017/02/23)
A unique and novel reaction between benzyl azides and aryl azides is described to synthesize aryl nitriles and anilines concurrently, which is catalyzed with a photoactivated diruthenium complex. N-Unsubstituted imines (N-H imines) are generated first from benzyl azides, followed by the hydrogen transfer reaction between N-H imines and aryl azides. A wide range of aryl nitriles and anilines were synthesized under neutral and mild reaction conditions.
Solvent-and catalyst-free reaction of (aminomethyl)phosphonates with epoxides: Synthesis of novel {[(2-hydroxyethyl)amino]methyl}phosphonates
Kaboudin, Babak,Sorbiun, Mina
experimental part, p. 284 - 289 (2011/04/12)
Uncatalyzed reaction of epoxides with (aminomethyl)phosphonates for the synthesis of novel {[(2-hydroxyethyl)amino]methyl}phosphonates is described. Treatment of (aminomethyl)phosphonates with epoxides without any catalyst and under solvent-free condition
Correlation analysis of reactivity in the oxidation of substituted benzylamines by pyridinium hydrobromide perbromide
Garg, Dimple,Goyal, Archana,Kothari, Seema
, p. 935 - 941 (2007/10/03)
The oxidation of benzylamine and twenty-seven ortho-, meta- and para-substituted benzylamines by pyridinium hydrobromide perbromide (PHPB), in dimethylsulphoxide (DMSO), leads to the formation of the corresponding aldimines. The reactions are of first order with respect to both PHPB and the amine. The oxidation of deuterated benzylamine exhibited a substantial kinetic isotope effect (kII/kD = 3.20 at 303 K). An addition of pyridinium bromide does not affect the rate. PHPB itself has been postulated as the reactive oxidizing species. The rates of the oxidation of para- and meta-substituted benzylamines were correlated with Taft's and Swain's field and resonance substituent constants. The oxidation of para-substituted benzylamines showed an excellent correlation with Taft's σI and σRBA values; the meta-compounds correlated best with σI and σR0 values. Rates of the ortho-substituted compounds showed a significant correlation with Charton's triparametric equation. Suitable mechanism has been proposed.
Kinetics and mechanism of the oxidation of substituted benzylamines by oxo(salen)manganese(V) complexes
Dubey, Rashmi,Kotai, Laszlo,Banerji, Kalyan K.
, p. 218 - 235 (2007/10/03)
The oxidation of substituted benzylamines by substituted oxo(salen)manganese(V) complexes, in acetonitrile, leads to the formation of the corresponding aldimines. The reaction is first order with each of the amine and the Mn(V) complex. The oxidation of [1,1-2H2]benzylamine exhibited the presence of substantial kinetic isotope effects. The rates of oxidation of 19 amines by 4 Mn(V) complexes have been determined. Correlation analyses of the rates of oxidation of the 19 monosubstituted benzylamines were performed with various single and multiparametric equations. The rates of the oxidation showed excellent correlations in terms of Yukawa-Tsuno and Brown's equations. The polar reaction constants are negative. The rate of reduction of the substituted Mn(V) complexes showed an excellent correlation in terms of the Hammett equation with positive reaction constants. The reactivity-selectivity principle (RSP) is obeyed in this reaction. The validity of RSP was verified by Exner's mathematical procedure. Suitable mechanisms have been discussed.
Kinetics and mechanism of the oxidation of substituted benzylamines by hexamethylenetetramine-bromine
Dubey, Rashmi,Kothari, Seema,Banerji, Kalyan K.
, p. 103 - 107 (2007/10/03)
The oxidation of substituted benzylamines by hexamethylenetetramine-bromine (HABR) to the corresponding aldimines is first order with respect to each the amine and HABR. It is proposed that HABR itself is the reactive oxidizing species. The oxidation of deuterated benzylamine (PhCD2NH2) indicated a substantial kinetic isotope effect (kH/kD = 5.60 at 293 K). This confirmed the cleavage of an α-C-H bond in the rate-determining step. Correlation analyses of the rates of oxidation of 20 monosubstituted benzylamines were performed with various single-and multi-parametric equations. The rates of the oxidation showed excellent correlations in terms of the Yukawa-Tsuno and Brown equations. The polar reaction constants were negative. The oxidation exhibited extensive cross-conjugation, in the transition state, between the electron-donating substituents and the reaction centre. A mechanism involving a hydride ion transfer from the amine to HABR, in the rate-determining step, is proposed. Copyright
Correlation analysis of reactivity in the oxidation of substituted benzylamines by benzyltrimethylammonium tribromide
Sankhla, Rekha,Kothari, Seema
, p. 541 - 546 (2007/10/03)
The oxidation of benzylamine and twenty-seven ortho-, meta- and para-monosubstituted benzylamines by benzyltrimethylammonium tribromide (BTMAB), in dimethylsulphoxide (DMSO), leads to the formation of corresponding aldimines. The reaction is first order with respect to both BTMAB and the amine. The oxidation of deuterated benzylamine exhibited a substantial kinetic isotope effect. Addition of benzyltrimethylammonium bromide does not affect the rate. Tribromide ion has been postulated as the reactive oxidizing species. The rates of the oxidation of para- and meta-substituted benzylamines showed excellent correlation in terms of both Taft's dual substituent-parameter and Charton's triparametric LDR equations, whereas the ortho-substituted compounds exhibited the best correlation with the Charton's tetraparametric LDRS equation. The oxidation of para-substituted benzylamines is more susceptible to the delocalization effect than is the oxidation of ortho- and meta-substituted compounds, which display a greater dependence on the field effect. The low positive value of the η suggests the presence of an electron-deficient centre in the rate-determining transition state with less charge separation. A suitable mechanism has been proposed.
