922185-81-7

Basic information

• Product Name: [PtMe(dimethylsulfoxide-S)(3-PhCH₂NCH-thiophen-2-yl)]
• CAS NO: 922185-81-7
• Molecular Weight: 488.534
• Mol File: 922185-81-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [PtMe(dimethylsulfoxide-S)(3-PhCH₂NCH-thiophen-2-yl)](CAS DataBase Reference)
• NIST Chemistry Reference: [PtMe(dimethylsulfoxide-S)(3-PhCH₂NCH-thiophen-2-yl)](922185-81-7)
• EPA Substance Registry System: [PtMe(dimethylsulfoxide-S)(3-PhCH₂NCH-thiophen-2-yl)](922185-81-7)

Safety Data

• Hazardous Substances Data: 922185-81-7(Hazardous Substances Data)

Upstream product

• 278778-73-7 [PtMe(3-(PhCH₂NCH)C₄H₂S)SMe₂] 
• 67-68-5 dimethyl sulfoxide 

Downstream Products

• 922185-85-1 [PtMe2(3-PhCH2NCH(C4H2S))(μ-I)]2 

Relevant articles and documents

Reactivity of cyclometallated platinum complexes with chiral ligands

The reaction of [Pt2Me4(μ-SMe2)2] with 3-substituted iminic thiophenes and 2-phenylpyridine givesplatinum (II) [C,N] cyclometallated complexes which contain a labile li gand (SMe2 or CH3CN). Several platinum (II) complexes have been synthesized by substitution reactions with phosphine or sulfoxide ligands to introduce, in most cases, a second chiral center. Thenew complexes' reactions with methyl iodide were subsequently studied a nd showed results that are dependent on the steric and electronic effects of both the cyclometallated ligand and the ancillary phosphine or sulfoxide ligand. The structure of [PtMe((R)-C10H7CHMeNCHC4H2S)(CH3CN)], a synthetic precursor, is also reported.