92219-91-5Relevant academic research and scientific papers
Stereoselective additions to the alkoxycarbene cations [(η5-C5H5)Fe(CO)(PPh 3)(=CROMe)]+ (R = H, Et)
Baird, Gordon J.,Davies, Stephen G.,Maberly, Timothy R.
, p. 1764 - 1765 (2008/10/08)
Nucleophilic addition reactions to the cations [(η5-C5H5)Fe(CO)(PPh 3)(=CROMe)]+ (R = H, Et) are highly stereoselective. The product diastereoisomers [(η5-C5H5)Fe(CO)(PPh3)(CHEtOMe)] undergo epimerization in methanol prior to formation of (E)-[(η5-C5H5)Fe(CO)-(PPh 3)(CH=CHMe)].
