92237-27-9

Basic information

• Product Name: 2-deoxy-2-bromo-4,6-O-benzylidene-1,5-anhydro-D-altritol
• Synonyms: 2-deoxy-2-bromo-4,6-O-benzylidene-1,5-anhydro-D-altritol
• CAS NO: 92237-27-9
• Molecular Weight: 315.164
• Mol File: 92237-27-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-deoxy-2-bromo-4,6-O-benzylidene-1,5-anhydro-D-altritol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-deoxy-2-bromo-4,6-O-benzylidene-1,5-anhydro-D-altritol(92237-27-9)
• EPA Substance Registry System: 2-deoxy-2-bromo-4,6-O-benzylidene-1,5-anhydro-D-altritol(92237-27-9)

Safety Data

• Hazardous Substances Data: 92237-27-9(Hazardous Substances Data)

Upstream product

• 65391-44-8 1,5-anhydro-4,6-O-(R)-benzylidene-D-glucitol 
• 65371-07-5 2,3-di-O-p-tolylsulphonyl-4,6-O-benzylidene-1,5-anhydro-D-glucitol 
• 92283-88-0 1,5:2,3-dianhydro-4,6-O-benzylidene-D-allitol 
• 1730-25-2 allylmagnesium bromide 

Relevant articles and documents

Unusual Stereochemistry in the Copper-catalyses Ring Opening of a Carbohydrate Oxirane with Vinylmagnesium Bromide

The oxirane ring of 4,6-O-benzylidene-1,5:2,3-dianhydro-D-allitol (1) opened regio- and stereo-selectively at C-2 with Me2CuLi and allylmagnesium chloride in the presence of catalytic amounts of CuI.With vinylmagnesium bromide, however, the ring opening of (1) was regioselective but a mixture of stereoisomers (10) and (12) was obtained corresponding to retention and inversion at C-2.A mechanism for the formation of the anomalous retention product (12) is proposed.