922721-28-6Relevant articles and documents
A highly efficient and aerobic protocol for the synthesis of N-heteroaryl substituted 9-arylcarbazolyl derivatives via a palladium-catalyzed ligand-free Suzuki reaction
Rao, Xiaofeng,Liu, Chun,Qiu, Jieshan,Jin, Zilin
supporting information, p. 7875 - 7883 (2013/06/27)
A palladium-catalyzed aerobic and ligand-free Suzuki reaction in aqueous ethanol has been developed for the synthesis of N-heteroaryl substituted 9-arylcarbazolyl derivatives. A number of N-heteroaryl halides, namely 2-halogenated pyridines, 2-bromoquinoline, 5-bromopyrimidine and 2-chloropyrazine, were coupled with 4-(9H-carbazol-9-yl)phenylboronic acid (CPBA) or 9-phenyl-9H-carbazol-3-ylboronic acid (PCBA) efficiently to afford good to excellent yields in a short reaction time. Moreover, the catalytic system of Pd(OAc)2-EtOH/H2O-K2CO3 was successfully extended to the cross-couplings of N-heteroaryl halides with various arylboronic acids. The results demonstrated that the cross-coupling reaction in the present protocol was promoted by oxygen.
Multifunctional iridium complexes based on carbazole modules as highly efficient electrophosphors
Wong, Wai-Yeung,Ho, Cheuk-Lam,Gao, Zhi-Qiang,Mi, Bao-Xiu,Chen, Chin-Hsin,Cheah, Kok-Wai,Lin, Zhenyang
, p. 7800 - 7803 (2007/10/03)
(Figure Presented) Getting the green light: Highly efficient organic light-emitting diodes (OLEDs) have been synthesized from robust green-electrophosphorescent IrIII complexes based on carbazole derivatives (see picture, HT = hole transporting, EL = electroluminescence). The combination of short triplet lifetime, high emission efficiency, and improved charge-transporting properties allows these OLEDs to achieve peak efficiencies of 12% photons per electron and 38 cd A-1.