92284-55-4

Basic information

• Product Name: 3-Cyclohexen-1-yl, 1,3-bis(1,1-dimethylethyl)-2,5-dioxo-6-[(trifluoromethyl)thio]-
• CAS NO: 92284-55-4
• Molecular Formula: C15H20F3O2S
• Molecular Weight: 321.384
• Mol File: 92284-55-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Cyclohexen-1-yl, 1,3-bis(1,1-dimethylethyl)-2,5-dioxo-6-[(trifluoromethyl)thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Cyclohexen-1-yl, 1,3-bis(1,1-dimethylethyl)-2,5-dioxo-6-[(trifluoromethyl)thio]-(92284-55-4)
• EPA Substance Registry System: 3-Cyclohexen-1-yl, 1,3-bis(1,1-dimethylethyl)-2,5-dioxo-6-[(trifluoromethyl)thio]-(92284-55-4)

Safety Data

• Hazardous Substances Data: 92284-55-4(Hazardous Substances Data)

Upstream product

• 372-64-5 Bis(trifluoromethyl)disulfid 
• 719-22-2 2,6-Di-tert-butyl-1,4-benzoquinone 

Relevant articles and documents

Radical Intermediates in the Photoreaction between Disulfides and Acylsilanes

Photolysis of cylopropane solutions of a number of disulfides RSSR (R = Me, n-Bu, CF3) in the presence of acylsilanes R'C(O)SiMe3 led to radicals of general structure R'C(OSiMe3)SR which have been detected by EPR spectroscopy.The structure of the observed paramagnetic species has been ascertained by producing PhC(OSiMe3)SMe via an alternative route, i.e., by reacting Me3Si radicals with the thio ester PhC(O)SMe.The lifetime of these radicals varies considerably with the bulkiness of the substituents in the neighborhood of the radical center.The decay rates as a funct ion of temperature, together with the corresponding activation parameters, have been determined for the hindered t-BuC(OSiMe3)SCF3 radical; it is suggested that the decay process involves an equilibrium with a dimeric species.A number of possible reaction sequences leading to these radicals have been examined, although the actual mechanism is as yet unclear.